Product ID:3084 URETHANE FLEXIBLE ADDITIVE
MSDS Date:04/01/1991
FSC:8010
NIIN:00F019271
MSDS Number: BYHVL

SHERWIN-WILLIAMS CO/MARTIN SENOUR CO

101 PROSPECT AVE N W
CLEVELAND, OH 44115-1042
US

Emergency Phone: 216-566-2917/216-566-2902

Info Phone: 216-566-2902/216-566-2917

Cage: 54636

SHERWIN-WILLIAMS CO THE

CLEVELAND, OH 44115-1042 US

Telephone: 800-251-2486/216-566-2242

Cage: 54636

TOLUENE (IARC CARC- GROUP 3) *95-4*

CAS: 108-88-3

RTECS: XS5250000

Fraction By Weight: 47%

OSHA PEL 100 PPM

ACGIH TLV: 100 PPM

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

SOLVENT NAPHTHA, PETROLEUM, LIGHT AROMATIC, HIGH FLASH

CAS: 64742-95-6

RTECS: WF3400000

Fraction By Weight: 2%

ACGIH TLV: 100 PPM

BUTYL ACETATE (N-BUTYL ACETATE) *95-4*

CAS: 123-86-4

RTECS: AF7350000

Fraction By Weight: 2%

OSHA PEL 710 MG/CUM

ACGIH TLV: 713 MG/CUM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

HEXAMETHYLENE DIISOCYANATE POLYMER

Fraction By Weight: 50%

ACGIH TLV: 0.5 MG/CUM

HEXAMETHYLENE DIISOCYANATE

CAS: 822-06-0

RTECS: MO1740000

Fraction By Weight: 0.15%

ACGIH TLV: 0.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

4.08 LBS/GAL

RTECS: 9999999VO

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:IRRITATION OF EYES, SKIN & RESPIRATORY
SYSTEM, CNS DEPRESSION & DEATH. SKIN: ALCOHOLS & ACETATES CAN BE
ABSORBED. OVEREXPOSURE TO SOLVENTS MAY CAUSE ADVERSE EFFECTS TO THE
LIVER, URINARY, BLOOD FORMIN G, CARDIO-VASCULAR & REPRODUCTIVE
SYSTEMS. OVEREXPOSURE TO SOLVENTS MAY CAUSE PERMANENT BRAIN &
NERVOUS SYSTEM DAMAGE.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:IRRITATION, UNCONSCIOUSNESS, HEADACHE,
DIZZINESS, NAUSEA, LOSS OF COORDINATION, REDNESS, ITCHING, BURNING
SENSATION.
Medical Cond Aggravated by Exposure:PERSONS SENSITIVE TO ISOCYANATES,
CHRONIC LUNG/BREATHING PROBLEMS.

First Aid:INHALATION: REMOVE TO FRESH AIR. SKIN: WASH AREA THOROUGHLY
W/SOAP & WATER. EYES: FLUSH W/LARGE AMOUNTS OF WATER FOR 15 MINS.
OBTAIN MEDICAL ATTENTION IN ALL CASES.

Flash Point:43F
Lower Limits:0.5
Upper Limits:6.7
Extinguishing Media:CO2, DRY CHEMICAL, FOAM
Fire Fighting Procedures:WEAR FULL PROTECTIVE EQUIMENT & SCBA. WATER
SPRAY MAY BE INEFFECTIVE. IF WATER IS USED, FOG NOZZLES ARE
PREFERABLE. WATER MAY BE USED TO COOL CLOSED CONTAINERS.
Unusual Fire/Explosion Hazard:CLOSED CONTAINERS MAY EXPLODE WHEN
EXPOSED TO EXTREME HEAT. APPLICATION TO HOT SURFACES REQUIRES
SPECIAL PRECAUTIONS.

Spill Release Procedures:REMOVE SOURCES OF IGNITION. VENTILATE & REMOVE
W/INERT ABSORBENT. USE APPROPRIATE PROTECTIVE EQUPMENT. COVER
W/ABSORBENT. DEACTIVATE AFTER 10 MINS, COLLECT IN OPEN CONTAINERS &
ADD MORE AMMONIA. COVER LOOSELY. WASH AREA W/SOAP & WATER.
Neutralizing Agent:10% AMMONIA HYDROXIDE SOLUTION (HOUSEHOLD AMMONIA).

Handling and Storage Precautions:KEEP AWAY FROM HEAT, SPARS & OPEN
FLAME. DURING USE & UNTIL VAPORS ARE GONE: KEEP AREA VENTILATED,
DON'T SMOKE & EXTINGUISH SOURCES OF IGNITION.
Other Precautions:CONSULT NPPA CODE. USE APPROVED BONDING & GROUNDING
PROCEDURES. KEEP CONTAINER CLOSED WHEN NOT IN USE. TRANSFER ONLY TO
APPROVED CONTAINERS W/COMPLETE & APPROPRIATE LABELING. DON'T TAKE
INTERNALLY. KE EP OUT OF REACH OF CHILDREN.

Respiratory Protection:WHERE OVERSPRAY IS PRESENT, A POSITIVE PRESSURE
AIR SUPPLIED RESPIRATOR SHOULD BE WORN. IF UNAVAILABLE, A PROPERLY
FITTED ORGANIC VAPOR PARTICULATE RESPIRATOR APPROVED BY NIOSH/MSHA.
Ventilation:LOCAL EXHAUST PREFERABLE. GENERAL EXHAUST ACCEPTABLE IF
EXPOSURES ARE MAINTAINED < APPLICABLE EXPOSURE LIMITS.
Protective Gloves:REQUIRED
Eye Protection:REQUIRED
Other Protective Equipment:SAFETY SPECTACLE W/UNPERFORATED SIDESHIELDS,
BARRIER CREAMS.
Work Hygienic Practices:REMOVE/LAUNDER CONTAMINATED CLOTHING BEFORE
REUSE. WASH HANDS AFTER USING.
Supplemental Safety and Health
INTENIONAL MISUSE BY DELIBERATELY CONCENTRATING & INHALING THE CONTENTS
CAN BE HARMFUL/FATAL. AVOID BREATHING VAPOR & SPRAY MIST. AVOID
CONTACT W/SKIN & EYES. HLTH HZRD CONT'D: MAY CAUSE ALLERGIC RESP
IRATORY/SKIN REACTION. THIS PRODUCT IS PHOTOCHEMICALLY REACTIVE.

Boiling Pt:B.P. Text:132-419F
Vapor Density:>1
Spec Gravity:0.88-0.99
Evaporation Rate & Reference:SLOWER THAN ETHER
Percent Volatiles by Volume:0-100

Stability Indicator/Materials to Avoid:YES
Stability Condition to Avoid:HEAT, SPARKS, OPEN FLAME, ELECTRICAL
EQUIPMENT & OTHER IGNITION SOURCES.
Hazardous Decomposition Products:BY FIRE: CO2, CO

Waste Disposal Methods:WASTE MUST BE TESTED FOR IGNITABILITY. DONT
INCINERATE CLOSED CONTAINER. INCINERATE IN APPROVED FACILITY
IAW/FEDERAL, STATE & LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.